週次 |
日期 |
單元主題 |
第1週 |
2/21 |
Introduction.
Bio-inorganic chemistry versus inorganic biochemistry.
Important metals in biochemistry.
Important issues in bio-inorganic chemistry.
X-ray spectroscopy. XANES and EXAFS. |
第2週 |
2/28 |
Holiday |
第3週 |
3/06 |
Electronic spectroscopy of copper centers.
Ligand- to- metal charge transitions.
Blue copper proteins.
Lecture 02 part B had been update. |
第4週 |
3/13 |
EPR spectroscopy of CuII. |
第5週 |
3/20 |
Binuclear and trinuclear copper proteins. |
第6週 |
3/27 |
Hemes and heme proteins.
Myoglobin, hemoglobin; cytochrome c. |
第7週 |
4/03 |
Term break. |
第8週 |
4/10 |
Electronic, EPR and Raman spectra of heme proteins.
Cytochrome c peroxidase; horseradish peroxidase; cytochrome P450. |
第9週 |
4/17 |
Non-heme iron proteins.
Hemerythrin; ribonucleotide reductase; soluble methane monooxygenase. |
第10週 |
4/24 |
Copper methane monooxygenase.
Tricopper clusters. C.H activation. |
第11週 |
5/01 |
Iron sulfur clusters.
Magnetic susceptibility.
Mossbauer spectroscopy. |
第12週 |
5/08 |
Nickel/iron hydrogenases.
Photosynthesis. |
第13週 |
5/15 |
Photo-oxidation of water.
Oxygen-evolving complex.
Manganese EPR. |
第14週 |
5/22 |
Cytochrome c oxidase.
Electron transfer, dioxygen chemistry, and redox-linked proton pumping.
Cytochrome bc1.
Bacterial oxidases.
NADH dehydrogenase. |
第15週 |
5/29 |
Nitrogen fixation.
Structure of nitrogenase. |
第16週 |
6/05 |
NO,NO]2-andSO3]2- reductases. |
第17週 |
6/12 |
Long-range electron transfer in chemistry and biology. |